Kenneth G. Caulton

Distinguished Professor of Chemistry

Indiana UniversityBloomington, IN

 

Publication List

 

Tsvetkov, Nikolay; Fan, Hongjun; Caulton, Kenneth G. An evaluation of monovalent osmium supported by the PNP ligand environment

Dalton Trans., 2011, 40, 1105-1110

 

 

Andino, Jose G.; Flores, Jaime A.; Karty, Jonathan A.; . Massa, Joseph P; Park, Hyunsoo; Tsvetkov, Nikolay P.; Wolfe, Robert J.; Caulton, Kenneth G.*

Ligand Influence on Metal Aggregation: a Unique Bonding Mode for Pyridylpyrrolides Inorg. Chem. 2010, 49, 7626–7628.

He, Tao; Tsvetkov, Nikolay P.; Andino, Jose G.; Gao, Xin-Feng; Fullmer, Benjamin C.; Caulton, Kenneth G..
 Mechanism of Heterolysis of H2 by an Unsaturated d8 Nickel Center: Via Tetravalent Nickel?
J. Amer. Chem. Soc., 2010, 132(3), 910-911.

 

Walstrom, Amy; Fan, Hongjun; Pink, Maren; Caulton, Kenneth G. Unexpected selectivity in electrophilic attack on (PNP)RuN.
Inorganica Chimica Acta 2010, 363(3), 633-636.

 

Walstrom, Amy G.; Pink, Maren; Yang, Xiaofan; Caulton, Kenneth G. Synthesis and reactivity of a Ru(I) dimer devoid of p -acid ligands.   Dalton Transactions.  2009,  6001-6006.

 

Tsvetkov, Nikolai P.; Laird, Matthew F.; Fan, Hongjun; Pink, Maren; Caulton, Kenneth G.. Surprising isomer preference on Ir(III), favoring facile H-C(sp3) bond cleavage.    Chemical Communications  2009,  4578-4580.

 

Laird, M. F.; Pink, M.; Tsvetkov, N. P.; Fan, H.; Caulton, K.G.. Unusual selectivity of a (pincer)Ni-hydride reacting with CO2. Dalton Transactions, 2009,  (8), 1283-1285.

 

Fan, H.; Fullmer, B. C.; Pink, M.; Caulton, K. G., [Ni{N(SiMe2CH2PtBu2)2}]+: direct observation of transannular Si-C(sp3) bond coordination.Angewandte Chemie, International Edition, 2008, 47(47), 9112-9114.

 

Verat, A. Y.; Pink, M.; Fan, H.; Fullmer, B. C.; Telser, J.; Caulton, K. G., Reactivity of the Radical NO With a Masked Form of 14 Valence Electron (PNP)Rh: Forming Rh(0, I or II)? Eur. J. Inorg. Chem., 2008,  (30), 4704-4709.

 

Verat, A. Y.; Fan, H.; Pink, M.; Chen, Y.-S.; Caulton, K. G., Spin state, structure, and reactivity of terminal oxo and dioxygen complexes of the (PNP)Rh moiety. Chem.—A Eur. J., 2008, 14(25), 7680-7686.

 

Walstrom, A. N.; Fullmer, B. C.; Fan, H.; Pink, M.; Buschhorn, D. T.; Caulton, K. G.. Influence of the Metal Orbital Occupancy and Principal Quantum Number on Organoazide (RN3) Conversion to Transition-Metal Imide Complexes. Inorg. Chem., 2008, 47(19), 9002-9009.

 

Verat, A. Y.; Pink, M.; Fan, H.; Tomaszewski, J.; Caulton, K. G., [(tBu2PCH2SiMe2)2N]RhI? Rapidly reversible H-C(sp3) and H-C(sp2) bond cleavage by rhodium(I).  Organometallics, 2008, 27(2), 166-168.

 

Lee, J.-H.; Caulton, K. G., J. Coupling of terminal alkynes by RuHXL2 (X = Cl or N(SiMe3)2, L = PiPr3).Organometallic Chem., 2008, 693(8-9), 1664-1673.

 

Lee, J.-H.; Pink, M.; Smurnyy, Y. D.; Caulton, K. G., Mechanism of alkyne conversion to carbyne by 14- or 16-electron Os(H)2ClL2X (L = PiPr3; X = OTf or B(C6H3(CF3)2)4).J. Organometallic Chem., 2008, 693(8-9), 1426-1438.

 

Buschhorn, D.; Pink, M.; Fan, H.; Caulton, K. G., Nitrogen-Ligated Iron Complexes: Photolytic Approach to the FeN+ Moiety.Inorg. Chem., 2008, 47(12), 5129-5135.

 

Fullmer, B. C.; Fan, H.; Pink, M.; Caulton, K. G.. O/C Bond Cleavage of CO2 by Ni.Inorg. Chem., 2008, 47(6), 1865-1867.

 

Fullmer, B. C.; Pink, M.; Fan, H.; Yang, X.; Baik, M.; Caulton, K. G., The Effect of One Valence Electron: Contrasting (PNP)Ni(CO) with (PNP)Ni(NO) to Understand the Half-Bent NiNO Unit. Inorg. Chem., 2008, 47(9), 3888-3892.

 

Ingelson, M. J.; Pink, M.; Fan, H.; Caulton, K. G., Redox Chemistry of the Triplet Complex (PNP)CoI. J. Amer. Chem. Soc., 2008, 130(13), 4262-4276.

 

Ingleson, M. J.; Fullmer, B. C.; Buschhorn, D. T.; Fan, H.; Pink, M.; Huffman, J. C.; Caulton, K. G., Influence of the d-Electron Count on CO Binding by Three-Coordinate [(tBu2PCH2SiMe2)2N]Fe, -Co, and –Ni. Inorg. Chem., 2008, 47(2), 407-409.

 

Rimmer, R. Dale; Grills, David C.; Fan, Hongjun; Ford, Peter C.; and Caulton, Kenneth G. , Metal-Dependent Reactivity Differences for Transients Formed by Flash Photolysis of (PNP)M(CO), M=Co and Rh.J. Amer. Chem. Soc., 2007, 129(50), 15430-15431.

 

Ingelson, M. J.; Pink, M.; Fan, H.; Caulton, K. G., Exploring the Reactivity of Four Coordinate PNPCoX with Access to Three Coordinate, Spin Triplet PNPCo. Inorganic Chemistry, 2007, 46(24), 10321-10334.

 

Fan, Hongjun ; and Caulton, Kenneth G., 2-Electron reduction of N2O yields a new ligand binding mode: N-Nitrosoimide.Polyhedron, 2007, 26, 4731-4736.

 

Walstrom, Amy; Pink, Maren; Fan, Hongjun ; Tomaszewski, John; and Caulton, Kenneth G., Radical (NO) and Nonradical (N2O) Reagents Convert a Ruthenium (IV) Nitride to the Same Nitrosyl Complex.Inorg. Chem., 2007, 46, 7704-7706.

 

Lee, Joo-Ho; Pink, Maren; Tomaszewski, John, Fan, Hongjun ; and Caulton, Kenneth G., Facile Hydrogenation of N2O by an Operationally Unsaturated Osmium Polyhydride. J. Amer. Chem. Soc., 2007, 129, 8706-8707.

 

Lee, Joo-Ho ; Vedernikov, Andrei N; Dye, David; and Caulton, Kenneth G., NO Binds to Unsaturated Os(IV) Polyhydrides as a Redox Reagent. J. Organometallic Chem., 2007, 692, 3121-3132.

 

Lee, Joo-Ho; Fan, Hongjun; Pink, Maren ; and Caulton, Kenneth G., Reactivity of NO with an Osmium Polyhydride: Reductive Elimination and Reductive Nitrosylation on the Path from Odd- to Even-Electron Molecules. New J. Chem., 2007, 31, 838-840.

 

Yang, Xiaofan; Walstrom, Amy; Tsvetkov, Nikolay; Pink, Maren ; and Caulton, Kenneth G., Influence of Chelate Substituents on Structure and Spin-State of Unsaturated [N(SiMe2CH2PtBu2)2]Ru-X.  Inorg. Chem., 2007, 46, 4612-4616.

 

Ozerov, Oleg V.; Watson, Lori A.; Pink, Maren ; and Caulton, Kenneth G., Operationally Unsaturated Pincer/Rhenium Complexes Form Metal Carbenes from Cycloalkenes and Metal Carbynes From Alkanes. J. Amer. Chem. Soc., 2007, 129, 6003-6016.