Kenneth G.
Caulton
Distinguished Professor of
Chemistry
Publication
List
![]()
Tsvetkov, Nikolay; Fan, Hongjun; Caulton, Kenneth G. An evaluation of monovalent osmium supported by the PNP ligand environment
Dalton Trans., 2011, 40, 1105-1110
Andino, Jose G.; Flores, Jaime A.; Karty, Jonathan A.; . Massa, Joseph P; Park, Hyunsoo; Tsvetkov, Nikolay P.; Wolfe, Robert J.; Caulton, Kenneth G.*
He, Tao; Tsvetkov, Nikolay P.; Andino, Jose G.; Gao, Xin-Feng; Fullmer, Benjamin C.; Caulton, Kenneth G.. Mechanism of Heterolysis of H2 by an Unsaturated d8 Nickel Center: Via Tetravalent Nickel?
Walstrom, Amy; Fan, Hongjun; Pink, Maren; Caulton, Kenneth G. Unexpected selectivity in electrophilic attack on (PNP)RuN.
Inorganica Chimica Acta 2010, 363(3), 633-636.
Walstrom, Amy G.; Pink, Maren; Yang, Xiaofan; Caulton,
Kenneth G.. Synthesis and reactivity of a Ru(I) dimer
devoid of p -acid ligands. Dalton Transactions. 2009,
6001-6006.
Tsvetkov, Nikolai P.; Laird, Matthew F.; Fan, Hongjun;
Pink, Maren; Caulton, Kenneth G.. Surprising isomer preference on Ir(III),
favoring facile H-C(sp3) bond cleavage.
Chemical Communications 2009, 4578-4580.
Laird, M. F.; Pink, M.; Tsvetkov, N. P.; Fan,
H.; Caulton, K.G.. Unusual selectivity of a
(pincer)Ni-hydride reacting with CO2.
Fan,
H.; Fullmer, B. C.; Pink, M.; Caulton, K. G., [Ni{N(SiMe2CH2PtBu2)2}]+:
direct observation of transannular Si-C(sp3) bond coordination.Angewandte Chemie, International Edition, 2008, 47(47), 9112-9114.
Verat, A. Y.; Pink, M.; Fan, H.;
Fullmer, B. C.; Telser, J.; Caulton, K. G., Reactivity of the Radical NO
With a Masked Form of 14 Valence Electron (PNP)Rh: Forming Rh(0, I or
II)? Eur.
J. Inorg. Chem., 2008, (30), 4704-4709.
Verat, A. Y.;
Fan, H.; Pink, M.; Chen, Y.-S.; Caulton, K. G., Spin state, structure, and
reactivity of terminal oxo and dioxygen complexes of the (PNP)Rh moiety. Chem.—A Eur. J., 2008, 14(25), 7680-7686.
Walstrom, A. N.;
Fullmer, B. C.; Fan, H.; Pink, M.; Buschhorn, D. T.; Caulton, K. G.. Influence of the Metal Orbital Occupancy and
Principal Quantum Number on Organoazide (RN3) Conversion to Transition-Metal
Imide Complexes. Inorg. Chem., 2008, 47(19), 9002-9009.
Verat, A. Y.; Pink, M.; Fan, H.; Tomaszewski, J.;
Caulton, K. G., [(tBu2PCH2SiMe2)2N]RhI?
Rapidly reversible H-C(sp3) and H-C(sp2) bond cleavage by
rhodium(I). Organometallics, 2008, 27(2), 166-168.
Lee, J.-H.;
Caulton, K. G., J. Coupling of terminal alkynes by RuHXL2 (X
= Cl or N(SiMe3)2, L = PiPr3).Organometallic Chem.,
2008, 693(8-9), 1664-1673.
Lee, J.-H.;
Pink, M.; Smurnyy, Y. D.; Caulton, K. G., Mechanism of alkyne conversion to carbyne by 14- or
16-electron Os(H)2ClL2X (L = PiPr3; X = OTf or
B(C6H3(CF3)2)4).J.
Organometallic Chem., 2008, 693(8-9), 1426-1438.
Buschhorn, D.; Pink, M.; Fan, H.; Caulton, K. G.,
Nitrogen-Ligated Iron Complexes: Photolytic Approach
to the FeN+ Moiety.Inorg. Chem., 2008, 47(12), 5129-5135.
Fullmer, B. C.;
Fan, H.; Pink, M.; Caulton, K. G.. O/C Bond Cleavage of CO2 by Ni.Inorg.
Chem., 2008, 47(6), 1865-1867.
Fullmer, B. C.;
Pink, M.; Fan, H.; Yang, X.; Baik, M.; Caulton, K. G., The Effect of One Valence Electron: Contrasting
(PNP)Ni(CO) with (PNP)Ni(NO) to Understand the Half-Bent NiNO Unit.
Inorg. Chem., 2008, 47(9), 3888-3892.
Ingelson, M.
J.; Pink, M.; Fan, H.; Caulton, K. G., Redox Chemistry of the
Triplet Complex (PNP)CoI. J.
Amer. Chem. Soc., 2008, 130(13), 4262-4276.
Ingleson, M. J.; Fullmer,
B. C.; Buschhorn, D. T.; Fan, H.; Pink, M.; Huffman, J. C.; Caulton, K. G., Influence of the d-Electron
Count on CO Binding by Three-Coordinate [(tBu2PCH2SiMe2)2N]Fe,
-Co, and –Ni. Inorg. Chem., 2008, 47(2), 407-409.
Rimmer, R. Dale; Grills, David C.;
Ingelson, M. J.; Pink, M.; Fan, H.; Caulton,
K. G., Exploring the Reactivity of
Four Coordinate PNPCoX with Access to Three Coordinate, Spin Triplet PNPCo. Inorganic Chemistry, 2007, 46(24), 10321-10334.
Walstrom, Amy;
Ozerov, Oleg V.; Watson, Lori A.;