Collision cross sections (in Å2) of singly-protonated polyaminoacids. a

 

nb

Glync

Alan

Valn

Thrn

Ilen

Leun

Glnn

Lysn

Hisn

Phen

Trpn

2

62

 

86.5

 

98.2

 

100.0

99.2

98.7

 

122.3

3

76

89.0

116.3

 

128.0

 

125.9

133.4

128.5

137.8

155.8

4

86

102.9

136.1

 

155.4

157.8

147.8

157.8

154.2

168.6

192.3

5

97

115.0

155.0

 

174.5

181.3

169.0

180.5

179.8

200.0

214.6

6

107

127.0

176.2

 

199.6

204.5

190.4

209.9

197.2

224.8

249.3

7

 

140.5

188.8

 

 

 

208.3

231.3

213.8

247.1

268.3

8

 

155.5

 

202.8

 

257.5

225.4

253.6

234.6

 

296.1

9

 

167.9

 

216.1

 

273.2

 

271.1

 

 

317.7

10

 

179.3

 

233.8

 

 

 

 

 

 

 

11

 

192.2

 

246.8

 

 

 

 

 

 

 

12

 

202.4

 

263.5

 

 

 

 

 

 

 

13

 

214.9

 

280.0

 

 

 

 

 

 

 

14

 

224.9

 

291.5

 

 

 

 

 

 

 

15

 

235.2

 

 

 

 

 

 

 

 

 

16

 

247.4

 

 

 

 

 

 

 

 

 

17

 

256.2

 

 

 

 

 

 

 

 

 

18

 

265.0

 

 

 

 

 

 

 

 

 

19

 

276.3

 

 

 

 

 

 

 

 

 

 

aUnless otherwise noted, values listed here were recorded by Henderson et al. using an ion trap/ion mobility/time-of-flight instrument (Henderson, S. C.; Li, J.; Counterman, A. E.; Clemmer, D. E., J. Phys. Chem. B  1999, 103, 8780.

 

bNumber of residues in the polyaminoacid.

 

cReported by Wyttenbach, T.; Bushnell, J. E.; Bowers, M. T. J. Am. Chem. Soc. 1998, 120, 5098.