Collision cross
sections (in Å2) of singly-protonated polyaminoacids. a
|
nb |
Glync |
Alan |
Valn |
Thrn |
Ilen |
Leun |
Glnn |
Lysn |
Hisn |
Phen |
Trpn |
|
2 |
62 |
|
86.5 |
|
98.2 |
|
100.0 |
99.2 |
98.7 |
|
122.3 |
|
3 |
76 |
89.0 |
116.3 |
|
128.0 |
|
125.9 |
133.4 |
128.5 |
137.8 |
155.8 |
|
4 |
86 |
102.9 |
136.1 |
|
155.4 |
157.8 |
147.8 |
157.8 |
154.2 |
168.6 |
192.3 |
|
5 |
97 |
115.0 |
155.0 |
|
174.5 |
181.3 |
169.0 |
180.5 |
179.8 |
200.0 |
214.6 |
|
6 |
107 |
127.0 |
176.2 |
|
199.6 |
204.5 |
190.4 |
209.9 |
197.2 |
224.8 |
249.3 |
|
7 |
|
140.5 |
188.8 |
|
|
|
208.3 |
231.3 |
213.8 |
247.1 |
268.3 |
|
8 |
|
155.5 |
|
202.8 |
|
257.5 |
225.4 |
253.6 |
234.6 |
|
296.1 |
|
9 |
|
167.9 |
|
216.1 |
|
273.2 |
|
271.1 |
|
|
317.7 |
|
10 |
|
179.3 |
|
233.8 |
|
|
|
|
|
|
|
|
11 |
|
192.2 |
|
246.8 |
|
|
|
|
|
|
|
|
12 |
|
202.4 |
|
263.5 |
|
|
|
|
|
|
|
|
13 |
|
214.9 |
|
280.0 |
|
|
|
|
|
|
|
|
14 |
|
224.9 |
|
291.5 |
|
|
|
|
|
|
|
|
15 |
|
235.2 |
|
|
|
|
|
|
|
|
|
|
16 |
|
247.4 |
|
|
|
|
|
|
|
|
|
|
17 |
|
256.2 |
|
|
|
|
|
|
|
|
|
|
18 |
|
265.0 |
|
|
|
|
|
|
|
|
|
|
19 |
|
276.3 |
|
|
|
|
|
|
|
|
|
aUnless otherwise noted, values listed here were
recorded by Henderson et al. using an ion trap/ion mobility/time-of-flight
instrument (Henderson, S. C.; Li, J.; Counterman, A. E.; Clemmer, D. E., J.
Phys. Chem. B 1999, 103,
8780.
bNumber of residues in the polyaminoacid.
cReported by Wyttenbach, T.; Bushnell, J. E.;
Bowers, M. T. J. Am. Chem. Soc. 1998, 120, 5098.