Kenneth G. Caulton

Year-wise listing of Publications:


2002       2001       2000

2002

  • Caulton, K. G., Ferrando-Miguel, G., Coalter, J. N., III, Gerard, H., Huffman, J. C. and Eisenstein, O. (2002). "Geminal dehydrogenation of ether and amine C(sp3)H2 groups by electron-rich Ru(II) and Os." Abstracts of Papers, 223rd ACS Na tional Meeting, Orlando, FL, United States, April 7-11, 2002: INOR-002.
  • Caulton, K. G., Marchenko, A.V., Vedernikov, A. N., Dye, D. F., Pink, M. and Zaleski, J. M. (2002). "H-atom transfer as a path to coordinated Nitroxyl, HN=O." Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, Aug ust 18-22, 2002: INOR-646.
  • Caulton, K. G., Ozerov, O. V., Watson, L. A., Huffman, J. C. and Pink, M. (2002). "Amide promoted reactivity of rhenium polyhydrides." Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002: INOR -356.
  • Caulton, K. G., Ozerov, O. V., Watson, L., Huffman, J. C. and Pink, M. (2002). "Transformations of alkenes and alkanes by amido rhenium polyhydrides." Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-2 2, 2002: INOR-554.
  • Ferrando-Miguel, G., Coalter, J. N., III, Gerard, H., Huffman, J. C., Eisenstein, O., & Caulton, K. G. (2002). Geminal dehydrogenation of ether and amine C(sp3)H2 groups by electron-rich Ru(ii) and Os. New Journal of Chemistry, 26(6), 687-7 00.
  • Ho, V. M., Watson, L. A., Huffman, J. C. and Caulton, K. G. (2002). "Double C(sp3) dehydrogenation as a route to coordinated Arduengo carbenes: Experiment and computation on comparative .pi.-acidity." Abstracts of Papers, 223rd ACS Nation al Meeting, Orlando, FL, United States, April 7-11, 2002: CHED-514.
  • Lee, J.-H. and Caulton, K. G. (2002). "Study of trihydride osmium(IV) complex, OsH3ClL2 (L=PiPr3) with the radical NO." Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002: INOR-647.
  • Marchenko, A. V., Vedernikov, A. N., Dye, D. F., Pink, M., Zaleski, J. M. and Caulton, K. G. (2002). "An Electron-Excessive Nitrosyl Complex: Reactivity of a Ligand-Centered Radical Leading to Coordinated HNO." Inorganic Chemistry 41(16): 4087-4089.
  • Vedernikov, A. N., Caulton, K. G. and Huffman, J. C. (2002). "Alkane and arene functionalization in Pt-pyridinophane systems." Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002: INOR-562.
  • Vedernikov, A. N., Caulton, K. G., Huffman, J. C. and Pink, M. (2002). "Room temperature C-H bond activation with PtMe2H(L)+ [L = [2,1,1]-(2,6)-pyridinophane]." Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002: INOR-351.
  • Vedernikov, A. N., Wu, P., Huffman, J. C. and Caulton, K. G. (2002). "Cu(I) and Cu(II) complexes of a pyridine-based pincer ligand." Inorganica Chimica Acta 330(1): 103-110.
  • Watson, L. A. and Caulton, K. G. (2002). "Assessing isomeric structures of pincer-ligated ruthenium and osmium polyhydrides using density functional calculations." Molecular Physics 100(4): 385-395.
  • Watson, L. A., Caulton, K. G., Evans, P. A. and Leahy, D.K. (2002). "Identification of the active catalyst-precursor and the mechanism of rhodium-catalyzed allylic substitutions." Abstracts of Papers, 224th ACS National Meeting, Boston, M A, United States, August 18-22, 2002: INOR-547.
  • Yandulov, D. V., & Caulton, K. G. (2002). Electrophilic (Li+) acceleration of C-H reductive elimination and oxidative addition reactions of Os(II)/Os(0) nitrosyl complexes. New Journal of Chemistry, 26(5), 498-502.
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2001

  • Baxter, D. V., Caulton, K. G., Chiang, W. C., Chisholm, M. H., DiStasi, V. F., Dutremez, S. G. and Folting, K. (2001). "Synthesis, structural characterization, thermolysis and volatility study of the Schiff base complex Cu[CH3C(O)CHC(NCH2CH2OCH3) CH3]2." Polyhedron 20(20): 2589-2595.
  • Baxter, D. V., Caulton, K. G., Chiang, W.-C., Chisholm, M. H., DiStasi, V. F., Dutremez, S. G., Martin, J. D. and Streib, W. E. (2001). "Synthesis and structural characterization of tricarbomethoxymethanate complexes of copper(II) and barium(II) and evaluation of their suitability for MOCVD applications." New J. Chem. 25(3): 400-407.
  • Caulton, K. G., Wu, P. and Vedernikov, A. N. (2001). "Copper Catalysis of Olefin Aziridination." Abstracts of Papers, 222nd ACS National Meeting, Chicago, IL, United States, August 26-30, 2001: INOR-490.
  • Caulton, K. G., Ozerov, O. V., Gerard, H., Watson, L. A., Patel, C. G. and Huffman, J. C. (2001). "Synthesis, reactivity, and structure of rhenium comlexes supported by pincer type diphosphinoamido ligands." Abstracts of Papers, 222nd ACS National Meeting, Chicago, IL, United States, August 26-30, 2001: INOR-229.
  • Caulton, K. G., Coalter, J. N., III, Ferrando, G., Gerard, H. and Eisenstein, O. (2001). "Geminal dehydrogenation of aliphatic ethers and amines by Ru(II) and Os(II)." Abstr. Pap. - Am. Chem. Soc. 221st: INOR-331.
  • Caulton, K. G. (2001). "Factors governing the equilibrium between metal-alkyl, alkylidene and alkylidyne: MCX2R, X-M:CXR and X2M.tplbond.CR." J. Organomet. Chem. 617-618: 56-64.
  • Coalter, J. N., III, Huffman, J. C. and Caulton, K. G. (2001). "Carbene transposition involving double dehydrogenation of an sp3 carbon." Chem. Commun. (Cambridge, U. K.)(13): 1158-1159.
  • Coalter, J. N., III and Caulton, K. G. (2001). "ROMP using heterocyclic carbenes bearing a hydride ligand. An improved synthesis of RuCl2(PR3)2(:CHMe)." New J. Chem. 25(5): 679-684.
  • Vedernikov, A. N., Caulton, K. G., Miftakhov, R. and Borisoglebski, S. V. (2001). "Synthesis and characterization of new chelating poly-(2,6)-pyridinepolymethane ligands and their platinum metal complexes." Abstracts of Papers, 222nd ACS National Meeting, Chicago, IL, United States, August 26-30, 2001: INOR-277.
  • Watson, L. A. and Caulton, K. G. (2001). "Structure and reactivity of pincer-ligated ruthenium hydrides." Abstracts of Papers, 222nd ACS National Meeting, Chicago, IL, United States, August 26-30, 2001: INOR-024.
  • Watson, L. A., Yandulov, D. V. and Caulton, K. G. (2001). "C-D0 (D0 = .pi.-donor, F) Cleavage in H2C:CH(D0) by (Cp2ZrHCl)n: Mechanism, Agostic Fluorines, and a Carbene of Zr(IV)." J. Am. Chem. Soc. 123(4): 603-611.
  • Yandulov, D. V., Bollinger, J. C., Streib, W. E. and Caulton, K. G. (2001). "Os(H)2NO(PiPr3)2+: Mechanism and Energetics of a Room Temperature Reversible Ethyl/Hydridoethylene Equilibrium and Contrasting Double Insertion of Acetylene." Organometallics 20(10): 2040-2046.
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2000

  • Caulton, K. G., Renkema, K. B., Koren, P. R., Davidson, E. R., Eisenstein, O., Gerard, H. and Huang, D. (2000). "Facile cleavage of C-F bonds by late transition metal complexes." Book of Abstracts, 219th ACS National Meeting, San Francisc o, CA, March 26-30, 2000: FLUO-026.
  • Coalter, J. N., Bollinger, J. C., Eisenstein, O. and Caulton, K. G. (2000). "R-Group reversal of isomer stability for RuH(X)L2(CCHR) vs. Ru(X)L2(CCH2R): access to four-coordinate ruthenium carbenes and carbynes." New J. Chem. 24(12): 925-927.
  • Caulton, K. G. (2000). Combined X-ray diffraction and density functional study of [Ni(NO)(.eta.5-Cp*)] in the ground and light-induced metastable states. Chemtracts, 13(2), 85-88.
  • Coalter, J. N., III, Huffman, J. C. and Caulton, K. G. (2000). "Ruthenium carbenes derived from cyclic ethers and amines." Abstr. Pap. - Am. Chem. Soc. 220th: INOR-526.
  • Coalter, J. N., III, Huffman, J. C. and Caulton, K. G. (2000). "Facile X-C(sp2) bond cleavage (X = H, R, OR, NR2) by .pi.-acid abstraction from aldehydes, esters, amides, amines, and imines." Abstr. Pap. - Am. Chem. Soc. 220th: INOR-210.
  • Coalter, J. N., III, Ferrando, G. and Caulton, K. G. (2000). "Geminal dehydrogenation of a C(sp3) CH2 group by unsaturated Ru(II) or Os(II)." New J. Chem. 24(11): 835-836.
  • Coalter, J. N., III, Huffman, J. C. and Caulton, K. G. (2000). "Cleavage of H-C(sp2) and C(sp2)-X Bonds (X = Alkyl, Aryl, OR, NR2): Facile Decarbonylation, Isonitrile Abstraction, or Dehydrogenation of Aldehydes, Esters, Amides, Amines, and Imine s by [RuHCl(PiPr3)2]2." Organometallics 19(18): 3569-3578.
  • Coalter, J. N., III, Huffman, J. C., Streib, W. E. and Caulton, K. G. (2000). "A New Class of Electron-Rich Unsaturated Molecules: Ru2HnX4-n(PiPr3)4, X = Anion." Inorg. Chem. 39(17): 3757-3764.
  • Coalter, J. N., III, Streib, W. E. and Caulton, K. G. (2000). "Reactivity of [RuHCl(PiPr3)2]2 with Functionalized Vinyl Substrates. The H2 Ligand as a Sensitive Probe of Electronic Structure." Inorg. Chem. 39(17): 3749-3756.
  • Coalter, J. N., III, Bollinger, J. C., Huffman, J. C., Werner-Zwanziger, U., Caulton, K. G., Davidson, E. R., Gerard, H., Clot, E. and Eisenstein, O. (2000). "Coordinated carbenes from electron-rich olefins on RuHCl(PPri3)2." New J. Chem. 24(1): 9-26.
  • Ferrando, G., Gerard, H., Eisenstein, O. and Caulton, K. G. (2000). "Unprecedented C-O cleavage: Isomerization from osmium carbene to carbyne or to vinylidene." Book of Abstracts, 219th ACS National Meeting, San Francisco, CA, March 26-30 , 2000: INOR-691.
  • Gemel, C., Folting, K. and Caulton, K. G. (2000). "New Approach to Ru(II) Pincer Ligand Chemistry. Bis(tert-butylaminomethyl)pyridine Coordinated to Ruthenium(II)." Inorg. Chem. 39(7): 1593-1597.
  • Gemel, C., Huffman, J. C., Caulton, K. G., Mauthner, K. and Kirchner, K. (2000). "Solution and solid-gas reactivity of unsaturated [RuCp(tmeda)]+ (tmeda = Me2NC2H4NMe2)." J. Organomet. Chem. 593-594: 342-353.
  • Gottschalk-Gaudig, T., Huffman, J. C., Gerard, H., Eisenstein, O. and Caulton, K. G. (2000). "Unsaturated Ru(0) Species with a Constrained Bis-Phosphine Ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2]." Inorg. Chem . 39(18): 3957-3962.
  • Huang, D., Koren, P. R., Folting, K., Davidson, E. R. and Caulton, K. G. (2000). "Facile and Reversible Cleavage of C-F Bonds. Contrasting Thermodynamic Selectivity for Ru-CF2H vs F-Os:CFH." J. Am. Chem. Soc. 122(37): 8916-8931 .
  • Huang, D., Bollinger, J. C., Streib, W. E., Folting, K., Young, V., Jr., Eisenstein, O. and Caulton, K. G. (2000). "A 14-Electron Ruthenium(II) Hydride, [RuH(CO)(PtBu2Me)2]BAr'4 (Ar' = 3,5-(C6H3)(CF3)2): Synthesis, Structure, and Reactivity towar d Alkenes and Oxygen Ligands." Organometallics 19(12): 2281-2290.
  • Huang, D., Streib, W. E., Eisenstein, O. and Caulton, K. G. (2000). "16-Electron ruthenium(0) complexes containing the Ru(NO)L2+ substructure: planar RuCH3(NO)L2 vs sawhorse [Ru(NO)(C:C(SiMe3)2)L2]+." Organometallics 19(10): 19 67-1972.
  • Watson, L. A., Coalter, J. N., III and Caulton, K. G. (2000). "Reactions of LiN(SiMe2CH2PR2)2 with unsaturated ruthenium hydrides." Abstr. Pap. - Am. Chem. Soc. 220th: INOR-504.
  • Watson, L. and Caulton, K. G. (2000). "Modification of H2C = CH(Do) by C-Do (Do = .pi.-donor) cleavage using Cp2ZrHCl." Book of Abstracts, 219th ACS National Meeting, San Francisco, CA, March 26-30, 2000: INOR-414.
  • Yandulov, D. V., Huffman, J. C. and Caulton, K. G. (2000). "An osmium hydrido methyl species via an unconventional methyl transfer." New J. Chem. 24(9): 649-650.
  • Yandulov, D. V., Huang, D., Huffman, J. C. and Caulton, K. G. (2000). "Structural Distortions in mer-M(H)3(NO)L2 (M = Ru, Os) and Their Influence on Intramolecular Fluxionality and Quantum Exchange Coupling." Inorg. Chem. 39(9) : 1919-1932.
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Last Updated: September 9, 2002
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